Right, just to check this...
Fitted the new alternator today, and found that it had the old-style connections on the back, so had to crimp on spade connectors to get around this (the original has ring terminals). So that was the fat red wire to one of the larger paired 'B+' terminals, and the thin blue wire to the 'D+' terminal.
Start the car up, and all seems fine - then started measuring voltages.
Voltage across the battery reads +13.82V. Seems good.
Alternator body to the +'ve terminal on the battery - +13.87V. Good.
Then tried to measure between B+ on the alternator to +'ve terminal on the battery, and got a massive spark as soon as I touched the lead to the terminal on the alternator. Not so good. Held it there, and the spark died down - touched to the +'ve on the battery, and we only have +0.03V. Not entirely sure this is good

Does this mean that no voltage is going from the alternator to the battery?
However, having had the engine running for about five to ten minutes, the voltage across the battery appears to be fine. Sitting around +13.80V, and going down but then climbing back up again, so seems to be charging. Also, no ignition light on the dash when running.
Does anyone know if this sounds normal? Not really sure what I'm looking for here.